WebI. THE RAW MATERIAL. The use of a soporific tisane or "tea" of poppy capsules has long been known in Europe, perhaps ever since the beginning of poppy cultivation there more than 3,000 years ago. However, the commercial manufacture of morphine direct from the poppy plant dates only from the 1920's, when it was begun in Hungary by Janos von … WebExternal links. Carbonate derivatives of 14β-hydroxycodeine "viz., 14β-hydroxy-6-O-(methoxycarbonyl)codeine, 6-O-methoxycarbonyl-14β-(methoxycarbonyloxy)codeine, and 14β-acetoxy-6-O-methoxy-carbonylcodeine, potential substrates for ring C modification in morphinane (sic) alkaloids, were synthesized for the first time." Russian Chemical Bulletin.
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